This study introduces a novel concept to provide both electric charging and hydrogen refueling at the same location. A hybrid hydrogen/electricity refueling station (HERS) powered only by solar photovoltaics in a remote area without access to the electrical grid is proposed. On-site hydrogen production stations are expected to play a key role in future power systems by absorbing renewable energy and supplying electricity during peak grid. The goal of this investigation is to develop a techno-economic optimization framework for the design of a stand-alone photovoltaic (PV)-driven hydrogen production and refueling station, with the explicit objective of minimizing the levelized cost of hydrogen (LCOH).